Regiodivergent hydrosilylation in the nickel(0)-catalyzed cyclization of 1,6-enynes
Dachang Bai, Ruoshi Cheng, Jiaxin Yang, Wenjie Xu, Xingge Chen, Junbiao Chang
Abstract
The divergent nickel(0)-catalyzed hydrosilylation/cyclization of 1,6-enynes has been developed, providing an efficient synthetic route for vinyl silanes or alkyl silanes from the same starting materials.
Topics & Concepts
HydrosilylationSilanesChemistryNickelCatalysisAlkylOrganic chemistrySilaneOrganoboron and organosilicon chemistryCatalytic Alkyne ReactionsCatalytic C–H Functionalization Methods