Litcius/Paper detail

Investigating the Antibacterial Properties of Inverse Vulcanized Sulfur Polymers

Jessica A. Smith, Ross Mulhall, Sean Goodman, George Fleming, Heather E. Allison, Rasmita Raval, Tom Hasell

2020ACS Omega86 citationsDOIOpen Access PDF

Abstract

More than 60 million tons of sulfur are produced as a byproduct of the petrochemical industry annually. Recently, the inverse vulcanization process has transformed this excess sulfur into functional polymers by stabilization with organic cross-linkers. These interesting new polymers have many potential applications covering diverse areas. However, there has been very little focus on the potential of these high-sulfur polymers for their antibacterial properties. These properties are examined here by exposing two common bacteria species, Escherichia coli (E. Coli) and Staphylococcus aureus (S. aureus), to two structurally different, inverse vulcanized sulfur polymers: sulfur-co-diisopropenyl benzene (S-DIB) and sulfur dicyclopentadiene (S-DCPD). We report the highest bacteria log reduction (>log 4.3) of adhered bacterial cells (S. aureus) to an inverse vulcanized sulfur polymer to date and investigate the potential pathways in which antibacterial activity may occur.

Topics & Concepts

VulcanizationSulfurPolymerDicyclopentadieneChemistryEscherichia coliStaphylococcus aureusBacteriaOrganic chemistryMaterials scienceNatural rubberBiochemistryBiologyPolymerizationGeneticsGeneSynthesis and properties of polymersAntimicrobial agents and applicationsSynthetic Organic Chemistry Methods