Recent advances in photoinduced amidyl radical-mediated remote C(sp <sup>3</sup> )–H activation <i>via</i> 1,5-hydrogen atom transfer
Min Liao, Yuanyuan Li, Meiling Ye, Chunjuan Liu
Abstract
This review highlights the recent advances in the functionalization of remote inert C(sp 3 )–H bonds triggered by nitrogen-centered radicals (NCRs) via photoinduced 1,5-hydrogen atom transfer processes.
Topics & Concepts
Surface modificationInertPhotochemistryRadicalAtom (system on chip)ChemistryRegioselectivityMoleculeChemical bondReaction mechanismNanotechnologyMaterials sciencePhotoinduced electron transferMechanism (biology)Combinatorial chemistryOrganic synthesisInert gasChemical reactionCatalytic C–H Functionalization MethodsRadical Photochemical ReactionsSynthesis and Catalytic Reactions