Donor modification of thermally activated delayed fluorescence photosensitizers for organocatalyzed atom transfer radical polymerization
Alexander M. Polgar, Shine H. Huang, Zachary M. Hudson
Abstract
TADF donor-acceptor conjugates were applied as photosensitizers for organocatalyzed organic atom transfer radical polymerization. A donor-modification strategy was found to dramatically improve the control over the polymerization.
Topics & Concepts
PhotochemistryChemistryAtom-transfer radical-polymerizationPolymerizationAcceptorFluorescenceRadical polymerizationChain transferPolymer chemistryPolymerOrganic chemistryCondensed matter physicsPhysicsQuantum mechanicsAdvanced Polymer Synthesis and CharacterizationPhotopolymerization techniques and applicationsOrganic Light-Emitting Diodes Research