The noncovalent dimerization of a G-quadruplex/hemin DNAzyme improves its biocatalytic properties
Yu Cheng, Mingpan Cheng, Jingya Hao, Guoqing Jia, David Monchaud, Can Li
Abstract
) are activated. This new biocatalytic system efficiently performs peroxidase- and peroxygenase-type biotransformations of a broad range of substrates, thus providing new perspectives for biotechnological application of GQs.
Topics & Concepts
HeminDeoxyribozymeG-quadruplexMonooxygenaseCofactorChemistryPeroxidaseHemeNon-covalent interactionsStereochemistryBiochemistryCombinatorial chemistryEnzymeDNAOrganic chemistryMoleculeCytochrome P450Hydrogen bondAdvanced biosensing and bioanalysis techniquesDNA and Nucleic Acid ChemistryBacteriophages and microbial interactions