Role of a Doped Support Strategy for Maintaining Stable Cu<sup><i>n</i>+</sup> Sites in Acetylene Hydrochlorination
Lijie Yang, Linfeng Li, Jian Li, Yongsheng Xu, Yanzhao Dong, Dongyang Xie, Zhenbang Liu, Qiangang Zhang, Ji Qi, Zihan Guo, Jinli Zhang, Haiyang Zhang
Abstract
A Cu-based catalyst, a developable catalyst in the acetylene hydrochlorination reaction, suffers from severe insufficient activity due to the reduction of Cu n + sites under a C 2 H 2 atmosphere. In this work, we have developed a doped support strategy to maintain more than 90% of Cu n + sites during the reaction via simply treating the mixture of melamine pyrophosphate and pristine activated carbon. Doped engineering for support plays dual positive roles in the acetylene hydrochlorination reaction: due to the interaction between Cu and doped sites, reduced C 2 H 2 molecules are easily desorbed at lower temperatures on the Cu sites to inhibit the reduction from Cu n + to Cu 0 during the reaction. Besides, element-doped sites also provide more adsorption sites for reactant molecules to decrease the internal diffusion distance. Based on the above benefits, the optimal catalyst (Cu/N,P 1/2 -AC) achieved an initial C 2 H 2 conversion of 97.8%, and the activity loss of the catalyst was only 14.2% in the long-term stability test at 200 h. Finally, this strategy is extended by other two doped precursors with obvious catalytic performance enhancement. This designed strategy for Cu-based catalysts provides a new appreciation for the acetylene hydrochlorination reaction.