Macrocycle supported dinuclear lanthanide complexes with different β-diketonate co-ligands displaying zero field single-molecule magnetic behaviour
Kuheli Pramanik, Yu‐Chen Sun, Paula Brandão, Narayan Ch. Jana, Xin‐Yi Wang, Anangamohan Panja
Abstract
Three different sets of isomorphous dinuclear Gd/Dy complexes with an uncommon macrocyclic ligand and β-diketonate co-ligands were reported in which Dy 2 analogues are zero field SMMs.
Topics & Concepts
ChemistryLanthanideMoleculeCrystallographyLigand (biochemistry)Zero (linguistics)StereochemistryIonReceptorOrganic chemistryBiochemistryPhilosophyLinguisticsMagnetism in coordination complexesLanthanide and Transition Metal ComplexesMetal-Catalyzed Oxygenation Mechanisms