Structural studies of a manganese(<scp>iii</scp>) complex with spin-crossover and thermochromic properties
David Villaman, Charles J. McMonagle, Michael R. Probert, Octavio Peña, Yanko Moreno, Mauricio Fuentealba
Abstract
A new Mn<sup>III</sup> complex exhibits a gradual spin crossover phenomenon with single crystal thermochromism. A comparative structural study was conducted using octahedral deviation parameters.
Topics & Concepts
ThermochromismSpin crossoverManganeseOctahedronCrystallographyCrossoverMaterials scienceChemistryCrystal structureCondensed matter physicsPhysicsMetallurgyComputer scienceArtificial intelligenceMagnetism in coordination complexesLanthanide and Transition Metal ComplexesMetal-Catalyzed Oxygenation Mechanisms