The design of hypercrosslinked polymers from benzyl ether self-condensing compounds and external crosslinkers
Robert T. Woodward
Abstract
Hypercrosslinked polymers were produced via the self-condensation of benzyl ether compounds, providing a one-component route to highly porous networks and significant reductions in catalyst waste compared to conventional routes. These compounds also represent a new class of external crosslinkers, able to impart improved textural properties when compared to standard aliphatic crosslinkers.
Topics & Concepts
EtherPolymerPolymer chemistryChemistryMaterials scienceOrganic chemistryChemical engineeringEngineeringCovalent Organic Framework ApplicationsMetal-Organic Frameworks: Synthesis and ApplicationsMembrane Separation and Gas Transport