NHC–Zn alkyl catalyzed cross-dehydrocoupling of amines and silanes
Adimulam Harinath, Himadri Karmakar, Devadkar Ajitaro Kisan, Hari Pada Nayek, Tarun K. Panda
Abstract
An NHC–zinc alkyl complex catalyzed CDC reaction of a wide range of primary and secondary amines and hydrosilanes to yield a substantial quantity of corresponding aminosilanes with good chemoselectivity at room temperature is reported.
Topics & Concepts
ChemistrySilanesChemoselectivityCatalysisCarbeneAlkylYield (engineering)ZincSubstrate (aquarium)Medicinal chemistryOrganic chemistryPolymer chemistrySilaneGeologyMetallurgyMaterials scienceOceanographyOrganoboron and organosilicon chemistryN-Heterocyclic Carbenes in Organic and Inorganic ChemistryCatalytic Cross-Coupling Reactions