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Research Progress on the Hydrogen Embrittlement Resistance Performance of High-Entropy Alloys

Xiao Kong, Hui Jiang, Yuting Lv, Wenlong Xie, Shuoyi Lu, Dingfeng Xu

2025Materials15 citationsDOIOpen Access PDF

Abstract

The concealment and delayed characteristics of hydrogen embrittlement (HE) pose significant challenges for the development of hydrogen-resistant materials. As a novel category of multi-principal-element alloys, high-entropy alloys (HEAs) have emerged as ideal candidates for the next generation of hydrogen-resistant alloys due to their unique design philosophy, which endows them with excellent mechanical properties, corrosion resistance, high-temperature stability, and hydrogen embrittlement resistance. In recent years, research on the hydrogen embrittlement resistance of HEAs has attracted extensive attention. This review systematically summarizes the hydrogen embrittlement mechanisms in both conventional alloys and HEAs, critically analyzes the contradictions and controversial issues in the current literature, proposes design strategies for hydrogen embrittlement-resistant HEAs, and discusses future research directions in this field.

Topics & Concepts

Hydrogen embrittlementMaterials scienceEmbrittlementHigh entropy alloysHydrogenCorrosionMetallurgyEnvironmental stress fractureMicrostructureChemistryOrganic chemistryHigh Entropy Alloys StudiesHydrogen embrittlement and corrosion behaviors in metalsHigh-Temperature Coating Behaviors