Single-molecule magnets within polyoxometalate-based frameworks
Malihe Babaei Zarch, Masoud Mirzaei, Maryam Bazargan, Sandeep K. Gupta, Franc Meyer, Joel T. Mague
Abstract
, different void shapes, and the existence of dinuclear Tb(III) units only in 2. Frameworks 1 and 2 were further characterized by dc and ac magnetic measurements and both exhibit slow relaxation of magnetization at low temperatures under an applied dc field. Their single-molecule magnet (SMM) properties are investigated, where weak field-induced SMM behaviour is observed at low temperatures in dynamic magnetic studies.
Topics & Concepts
PolyoxometalateLanthanideCationic polymerizationMagnetizationSingle-molecule magnetThermogravimetric analysisMaterials scienceCrystallographyMoleculeInfrared spectroscopyChemistryIonMagnetic fieldPolymer chemistryOrganic chemistryPhysicsQuantum mechanicsCatalysisMagnetism in coordination complexesMetal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and Applications