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Halogenated PETN derivatives: interplay between physical and chemical factors in explosive sensitivity

Nicholas Lease, Kyle D. Spielvogel, J. Davis, Jeremy T. Tisdale, Lisa M. Klamborowski, M. J. Cawkwell, Virginia W. Manner

2023Chemical Science12 citationsDOIOpen Access PDF

Abstract

(heat of explosion), due to the change in the number of trigger linkages removed from the starting material. In addition, this correlation appears more significant than other observed chemical or physical effects imparted on the material by different inert functional groups, such as heat of formation, heat of explosion, heat capacity, oxygen balance, and the crystal structure of the material.

Topics & Concepts

Explosive materialPentaerythritol tetranitrateEnergetic materialInertOxygen balanceSensitivity (control systems)ChemistryHeat capacityKineticsThermodynamicsMaterials scienceChemical physicsComputational chemistryOrganic chemistryOxygenQuantum mechanicsElectronic engineeringPhysicsEngineeringEnergetic Materials and CombustionThermal and Kinetic AnalysisCombustion and Detonation Processes
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