Nano‐Ni‐Induced Electronic Modulation of <scp>MoS<sub>2</sub></scp> Nanosheets Enables Energy‐Saving <scp>H<sub>2</sub></scp> Production and Sulfide Degradation
Fan Liu, Xinghong Cai, Yang Tang, Wenqian Liu, Qianwei Chen, Peixin Dong, Maowen Xu, Yangyang Tan, Shu‐Juan Bao
Abstract
Electrocatalytic hydrogen evolution and sulfion (S 2− ) recycling are promising strategies for boosting H 2 production and removing environmental pollutants. Here, a nano‐Ni‐functionalized molybdenum disulfide (MoS 2 ) nanosheet was assembled on steel mesh (Ni‐MoS 2 /SM) for use in sulfide oxidation reaction‐assisted, energy‐saving H 2 production. Experimental and theoretical calculation results revealed that anchoring nano‐Ni on high‐surface‐area slack MoS 2 nanosheets not only optimized catalyst adsorption of polysulfides but also played an important role in promoting hydrogen evolution reaction kinetics by absorbing OH ad , thereby greatly enhancing the catalytic performance toward sulfide oxidation reaction and hydrogen evolution reaction. Meanwhile, the Ni/MoS 2 ‐based hydrogen evolution reaction + sulfide oxidation reaction system achieved nearly 100% hydrogen production efficiency and only consumed 61% less power per kWh than the oxygen evolution reaction + hydrogen evolution reaction system, which suggested our proposed Ni‐MoS 2 and novel hydrogen production system are promising for sustainable energy production.