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Efficient Removal of Chromium(VI) Using a Novel Waste Biomass Chestnut Shell-Based Carbon Electrode by Electrosorption

Xiaofei Zhang, Bo Ren, Xiaonan Wu, Xin Yan, Yu Sun, Hongcheng Gao, Feng Qu

2021ACS Omega34 citationsDOIOpen Access PDF

Abstract

High Resolution Image Download MS PowerPoint Slide Biomass-derived porous carbon materials have a good application prospect in electrosorption because of their low cost, abundant natural resources, and excellent performance. In this work, three-dimensional interconnected structure porous carbon (CPC) was successfully synthesized from waste biomass chestnut shells by carbonization and chemical activation processes. The unique structure of CPC could offer superior double-layer capacitance and excellent conductivity. The as-obtained CPC was applied as an electrosorption electrode. In the deionization experiments, the removal efficiency of the CPC electrode in a 30 mg L –1 chromium(VI) aqueous solution at 1.0 V was 90.5%. The electrosorption follows pseudo-second-order kinetics. The CPC electrode also presented good regeneration performance in the regeneration test. These results demonstrate that the as-prepared carbonaceous material is an ideal material for capacitive deionization electrodes.

Topics & Concepts

Capacitive deionizationCarbonizationMaterials scienceElectrodeCarbon fibersBiomass (ecology)Chemical engineeringAqueous solutionChromiumCapacitanceSupercapacitorElectrochemistryChemistryComposite materialMetallurgyOrganic chemistryScanning electron microscopeGeologyComposite numberOceanographyPhysical chemistryEngineeringMembrane-based Ion Separation TechniquesMembrane Separation TechnologiesSupercapacitor Materials and Fabrication