Adsorption of Coomassie Brilliant Blue on a Novel Eco‐Friendly Nanogel from Simulated Water: Equilibrium, Kinetic, and Thermodynamic Studies
Suhail Ayoub Khan, Ankita Manchanda, Tabrez Alam Khan
Abstract
Abstract Herein a novel gum acacia‐alginate nanogel (GAA) was synthesized via ultrasound‐assisted crosslinking by DPPH and applied for the removal of coomassie brilliant blue (CBB) dye. The fabrication of GAA and its interaction with CBB was specified via FTIR, XRD, SEM, and TEM techniques. The process parameters at which maximum adsorption efficiency, q e (80.12 mg/g), and % efficiency >94 % were achieved include dosage (0.8 g/L), time (80 min), initial dye concentration (20 mg/L), and pH (6). Ultrasound‐assisted uptake was greater than stirring‐assisted due to acoustic cavitation′s hydrodynamic and thermal processes. Pseudo‐second‐order model described the adsorption kinetics and the diffusion mechanism suggested that the rate‐determining step was controlled by both the intraparticle diffusion and the liquid film models. Isotherms showed an excellent fit to the Freundlich model based on higher R 2 (0.998) and lower standard error of estimate values (SEE=0.367). The −Δ G ° values (−8.152, −8.292, −8.433, −8.586 kJ/mol) indicated that the adsorption process was feasible and spontaneous. The removal of CBB ensued via hydrogen bonding, electrostatic, π‐π, and n‐ π interactions. The maximum adsorption capacity of 182.096 mg/g, eco‐friendly characteristics along with regeneration competence depicted that GAA could be effective for scavenging CBB from wastewater.