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Effects of temperature and polyols on the ciprofloxacin hydrochloride-mediated micellization of sodium dodecyl sulfate

Shamim Mahbub, Sayma Akter, Luthfunnessa, Parul Akter, Md. Anamul Hoque, Malik Abdul Rub, Dileep Kumar, Yousef G. Alghamdi, Abdullah M. Asiri, Hurija Džudžević-Čančar

2020RSC Advances83 citationsDOIOpen Access PDF

Abstract

) of the pure surfactant is higher in the presence of the drug and is further enhanced through an increase in the CFH concentration in water/polyols media. Different thermodynamic parameters, such as the Gibbs free energy of micellization , standard enthalpy , entropy , different transfer energies and enthalpy-entropy compensation parameters of micellization were determined and illustrated in detail to compare these parameters between the pure SDS and SDS + CFH mixture in polyols media. The negative values of for the SDS/SDS + CFH mixture in all cases indicate spontaneous micelle formation. The and values indicate the presence of both hydrophobic and electrostatic interactions amongst the studied components.

Topics & Concepts

ChemistrySodium dodecyl sulfateCritical micelle concentrationMicelleEnthalpyPulmonary surfactantCiprofloxacin HydrochlorideThermodynamics of micellizationChromatographyGibbs free energyAqueous solutionOrganic chemistryThermodynamicsAntibioticsCiprofloxacinPhysicsBiochemistrySurfactants and Colloidal SystemsChemical and Physical Properties in Aqueous SolutionsElectrostatics and Colloid Interactions
Effects of temperature and polyols on the ciprofloxacin hydrochloride-mediated micellization of sodium dodecyl sulfate | Litcius