Support Effect of Metal–Organic Frameworks on Ethanol Production through Acetic Acid Hydrogenation
Shotaro Yoshimaru, Masaaki Sadakiyo, Nobutaka Maeda, Miho Yamauchi, Kenichi Kato, Jenny Pirillo, Yuh Hijikata
Abstract
support plays an important role in high EtOH selectivity by suppressing the formation of the byproduct, ethyl acetate (AcOEt), due to its relatively weak adsorption behavior for EtOH rather than AcOH.
Topics & Concepts
CatalysisMetal-organic frameworkAcetic acidSelectivityAdsorptionSubstrate (aquarium)Materials scienceEthanolYield (engineering)Inorganic chemistryEthyl acetateChemistryChemical engineeringNuclear chemistryOrganic chemistryMetallurgyEngineeringOceanographyGeologyMetal-Organic Frameworks: Synthesis and ApplicationsCatalysis and Hydrodesulfurization StudiesCatalytic Processes in Materials Science