Zn(<scp>ii</scp>) complexes with thiazolyl–hydrazones: structure, intermolecular interactions, photophysical properties, computational study and anticancer activity
Jovana B. Araškov, Aleksandar Višnjevac, Jasminka Popović, Vladimir Blagojević, Henrique S. Fernandes, Sérgio F. Sousa, Irena Novaković, José M. Padrón, Berta Barta Holló, Miguel Monge, María Rodríguez‐Castillo, José M. López‐de‐Luzuriaga, Nenad R. Filipović, Tamara R. Todorović
Abstract
Title ligands and their symmetrical octahedral complexes are not photoluminescent, contrary to other synthesized asymmetrical complexes. In comparison to the ligands, the complexes showed improved antiproliferative activity and lower toxicity.
Topics & Concepts
Intermolecular forceOctahedronChemistryPhotoluminescenceStereochemistryCombinatorial chemistryCrystallographyMoleculeCrystal structureMaterials scienceOrganic chemistryOptoelectronicsMetal complexes synthesis and propertiesSynthesis and biological activityClick Chemistry and Applications