Rechargeable nickel–3D zinc batteries: An energy-dense, safer alternative to lithium-ion
Joseph F. Parker, Christopher N. Chervin, Irina R. Pala, Meinrad Machler, Michael F. Burz, Jeffrey W. Long, Debra R. Rolison
Abstract
Zinc can compete with lithium Although lithium-based batteries are ubiquitous, there are still challenges related to their longevity and safety, as well as concerns about material availability. Aqueous rechargeable batteries based on zinc might provide an alternative, but they have been plagued by the formation of dendrites during cycling. Parker et al. show that when zinc is formed into three-dimensional sponges, it can be used with nickel to form primary batteries that allow for deep discharge. Alternatively, the sponges can be used to produce secondary batteries that can be cycled thousands of times and can compete with lithium ion cells. Science , this issue p. 415