Litcius/Paper detail

Electrochemical CO<sub>2</sub> Reduction in the Presence of Impurities: Influences and Mitigation Strategies

Nia J. Harmon, Hailiang Wang

2022Angewandte Chemie International Edition50 citationsDOI

Abstract

Abstract The electrochemical conversion of waste CO 2 into useful fuels and chemical products is a promising approach to reduce CO 2 emissions; however, several challenges still remain to be addressed. Thus far, most CO 2 reduction studies use pure CO 2 as the gas reactant, but CO 2 emissions typically contain a number of gas impurities, such as nitrogen oxides, oxygen gas, and sulfur oxides. Gas impurities in CO 2 can pose a significant obstacle for efficient CO 2 electrolysis because they can influence the reaction and catalyst. This Minireview highlights early examples of CO 2 reduction studies using mixed‐gas feeds, explores strategies to sustain CO 2 reduction in the presence of gas impurities, and discusses their implications for future progress in this emerging field.

Topics & Concepts

ImpurityElectrolysisElectrochemistryCatalysisSulfurNatural gas fieldNitrogenMaterials scienceChemistryEnvironmental scienceInorganic chemistryNatural gasElectrodeMetallurgyOrganic chemistryPhysical chemistryElectrolyteCO2 Reduction Techniques and CatalystsAdvanced Photocatalysis TechniquesAmmonia Synthesis and Nitrogen Reduction