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Photoredox relay-catalyzed <i>gem</i>-difluoroallylation of alkyl iodides

Yuanqiang Guo, Yunpeng Cao, Hongjian Song, Yuxiu Liu, Qingmin Wang

2021Chemical Communications32 citationsDOI

Abstract

Relay catalysis using a combination of Mn 2 (CO) 10 and an Iridium-based photocatalyst is reported. A broad scope of alkyl iodides was transformed into the corresponding gem -difluoroalkenes via C(sp 3 )–C(sp 3 ) bond construction.

Topics & Concepts

AlkylCatalysisIridiumChemistryScope (computer science)PhotocatalysisRelayCombinatorial chemistryMedicinal chemistryPhotoredox catalysisPhotochemistryOrganic chemistryPhysicsPower (physics)Computer scienceQuantum mechanicsProgramming languageFluorine in Organic ChemistryRadical Photochemical ReactionsCatalytic C–H Functionalization Methods
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