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Sb<sub>2</sub>S<sub>3</sub> as a low-loss phase-change material for mid-IR photonics

Adam Biegański, Marko Perestjuk, Rémi Armand, Alberto Della Torre, Capucine Laprais, Guillaume Saint‐Girons, Vincent Reboud, Jean‐Michel Hartmann, J.H. Tortai, Antonin Moreau, Julien Lumeau, Thach G. Nguyen, Arnan Mitchell, Christelle Monat, Sébastien Cueff, Christian Grillet

2024Optical Materials Express25 citationsDOIOpen Access PDF

Abstract

We study the mid-IR optical properties of Sb 2 S 3 – a phase-change material (PCM) with high potential for mid-IR integrated photonics. We show that Sb 2 S 3 exhibits a high refractive index contrast Δn ≈ 1 between its two phases and an extinction coefficient k below 10 −2 at mid-IR wavelengths (up to ∼10 µm). We study the impact of 100 nm Sb 2 S 3 cladding on SiGe-on-Si waveguides and experimentally show that it brings additional propagation loss below 1 dB/cm in the 3.3–3.9 µm wavelength range in both phases. These findings pave the way for new uses of Sb 2 S 3 in mid-IR integrated photonics.

Topics & Concepts

Materials sciencePhotonicsOpticsOptoelectronicsRefractive indexOptical materialsPhase (matter)Phase changePhysicsEngineering physicsQuantum mechanicsPhase-change materials and chalcogenidesChalcogenide Semiconductor Thin FilmsNonlinear Optical Materials Studies
Sb<sub>2</sub>S<sub>3</sub> as a low-loss phase-change material for mid-IR photonics | Litcius