Poly(hydroxyurethane): catalytic applicability for the cyclic carbonate synthesis from epoxides and CO<sub>2</sub>
Suguru Motokucho, Hiroshi Morikawa
Abstract
We have developed a synthetic methodology using poly(hydroxyurethane) as an organocatalyst for the chemical fixation of CO2 into epoxides, leading to the formation of five-membered cyclic carbonates with remarkably high selectivity and yields. The catalyzed reaction was applicable to various epoxides.
Topics & Concepts
CatalysisSelectivityChemistryCarbonateEpoxideCombinatorial chemistryPolymer chemistryOrganic chemistryCarbon dioxide utilization in catalysisAsymmetric Hydrogenation and CatalysisChemical Synthesis and Reactions