Porous SiO<sub>2</sub> Nanospheres Modified with ZrO<sub>2</sub> and Their Use in One-Pot Catalytic Processes to Obtain Value-Added Chemicals from Furfural
Rocío Maderuelo‐Solera, Stefan Richter, Carmen P. Jiménez‐Gómez, Cristina García‐Sancho, Francisco José García‐Mateos, Juana M. Rosas, Ramón Moreno‐Tost, Juan Antonio Cecilia, Pedro Maireles‐Torres
Abstract
Porous SiO 2 nanospheres were modified with different loadings of ZrO 2 to obtain catalysts with a Si/Zr molar ratio from 2.5 to 30. These materials were characterized by X-ray diffraction, transmission and scanning electron microscopies, N 2 adsorption-desorption at -196 C, X-ray photoelectron spectroscopy and pyridine and 2-6-dimethylpyridine thermoprogrammed desorption. The characterization of these catalysts has revealed that a high proportion of Zr favors the formation of Lewis acid sites, which are implied in catalytic transfer hydrogenation processes, whereas the low Bronsted acidity promotes a dehydration reaction, being possible to give rise to a large variety of products from furfural through consecutive reactions, such as furfuryl alcohol, i-propyl furfuryl ether, i-propyl levulinate, and -valerolactone, in a range of temperature of 110-170 C and 1-6 h of reaction.