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Multiple deuteration of triphenylphosphine and live-cell Raman imaging of deuterium-incorporated Mito-Q

Shogo Moriyama, Miyu Mae, Daiki Shibata, Hiroyuki Yamakoshi, Shinji Kajimoto, Takakazu Nakabayashi, Takayoshi Ishimoto, Kaiki Mogi, Hironao Sajiki, Shuji Akai, Yoshinari Sawama

2023Chemical Communications14 citationsDOI

Abstract

All aromatic C–H bonds of triphenylphosphine (PPh 3 ) were efficiently replaced by C–D bonds using Ru/C and Ir/C co-catalysts in 2-PrOH and D 2 O, an inexpensive deuterium source.

Topics & Concepts

DeuteriumTriphenylphosphineRaman spectroscopyChemistryCatalysisPhotochemistryNuclear chemistryOrganic chemistryPhysicsOpticsAtomic physicsChemical Reactions and IsotopesMass Spectrometry Techniques and ApplicationsAsymmetric Hydrogenation and Catalysis
Multiple deuteration of triphenylphosphine and live-cell Raman imaging of deuterium-incorporated Mito-Q | Litcius