Synthesis of low oxidation state zinc(<scp>i</scp>) complexes and their catalytic studies in the dehydroborylation of terminal alkynes
Rajata Kumar Sahoo, Sagrika Rajput, A. Ganesh Patro, Sharanappa Nembenna
Abstract
Herein, we report a structurally characterized CBG- supported low oxidation state zinc complex. Further, we have investigated zinc( i ) dimers as selective catalysts for the dehydroborylation of a wide range of terminal alkynes under mild conditions.
Topics & Concepts
HomolepticZincChemistryAcetylideDimerCatalysisStoichiometryConjugated systemOxidation stateStereochemistryCrystallographyMedicinal chemistryOrganic chemistryMetalPolymerOrganoboron and organosilicon chemistryCatalytic Cross-Coupling ReactionsN-Heterocyclic Carbenes in Organic and Inorganic Chemistry