Supramolecular “sergeants”: <i>in situ</i> and multi-level induction of chirality in helical assemblies of triarylamine trisamide monomers
Antoine Perennes, Quentin Sallembien, Weiwei Fang, Stéphane Grass, Jérôme Lacour, Laurent Bouteiller, Matthieu Raynal
Abstract
Triarylamine trisamide copolymers and catalysts are formed by chirality induction between a supramolecular “sergeant”, combining a (thio)urea-functionalized monomer (in grey) with a chiral anion (in blue), and various types of “soldiers” (in red).
Topics & Concepts
Supramolecular chemistryMonomerChirality (physics)In situAsymmetric inductionSupramolecular chiralityMaterials scienceChemistryPolymer chemistryCrystallographyPhysicsEnantioselective synthesisOrganic chemistryPolymerCatalysisCrystal structureNuclear physicsQuarkChiral symmetry breakingNambu–Jona-Lasinio modelSupramolecular Self-Assembly in MaterialsNonlinear Optical Materials ResearchCrystallography and molecular interactions