Anionic stitching polymerization of styryl(vinyl)silanes for the synthesis of sila-cyclic olefin polymers
Sho Ikeda, Ryo Shintani
Abstract
Anionic stitching polymerization of styryl(vinyl)silanes has been developed for the synthesis of a new type of silicon- and carbon-containing polymer possessing fused sila-bicyclic structures in the main chain. The obtained polymers were found to be thermally stable with relatively high glass-transition temperatures and highly transparent in the visible light region.
Topics & Concepts
SilanesPolymerPolymerizationPolymer chemistryMaterials scienceGlass transitionVinyl polymerOlefin fiberCarbon fibersChemistryOrganic chemistrySilaneComposite numberComposite materialOrganoboron and organosilicon chemistrySynthetic Organic Chemistry MethodsCatalytic Cross-Coupling Reactions