Synthesis of chiral functionalized UiO-66-NH<sub>2</sub>@SiO<sub>2</sub>and use of its domain-limiting effect for separating small enantiomers
Chunqiang Liu, Kaijun Quan, Hui Li, Xiaofeng Shi, Jia Chen, Hongdeng Qiu
Abstract
each exhibited enhanced stereoselectivity for small enantiomers and successfully achieved the separation of α-amino acid and small alkaline enantiomers. This study has provided a new concept for the design and synthesis of chiral materials for separating small-molecule enantiomers.
Topics & Concepts
EnantiomerLimitingMicroporous materialChemistryAmino acidDomain (mathematical analysis)Combinatorial chemistryStereochemistryOrganic chemistryMathematicsEngineeringMechanical engineeringMathematical analysisBiochemistryMetal-Organic Frameworks: Synthesis and ApplicationsGas Sensing Nanomaterials and SensorsChemical Synthesis and Characterization