Na<sub>6</sub>Sn<sub>3</sub>P<sub>4</sub>S<sub>16</sub>: Sn(<scp>ii</scp>)-chelated PS<sub>4</sub> groups inspired an ultra-strong SHG response
Chenyao Zhao, Bingbing Zhang, Xinyu Tian, Guoqiang Zhou, Jingjing Xu, Kui Wu
Abstract
Na 6 Sn 3 P 4 S 16 IR NLO thiophosphate exhibiting ultra-strong SHG response is originated from the collaborative polarization of edge-sharing SnS 4 and PS 4 units.
Topics & Concepts
ThiophosphateCrystallographyPolarization (electrochemistry)ChelationMaterials scienceChemistryInorganic chemistryPhysical chemistryOrganic chemistryCrystal Structures and PropertiesSolid-state spectroscopy and crystallographyNonlinear Optical Materials Research