Assembling diuranium complexes in different states of charge with a bridging redox-active ligand
Dieuwertje K. Modder, Mikhail S. Batov, Thayalan Rajeshkumar, Andrzej Sienkiewicz, Ivica Živković, Rosario Scopelliti, Laurent Maron, Marinella Mazzanti
Abstract
], 4. X-ray crystallography, electrochemistry, susceptibility data, EPR and DFT/CASSCF calculations are in line with their assignments. In complexes 2 and 4 the presence of the radical-bridge leads to slow magnetic relaxation.
Topics & Concepts
Bridging (networking)RedoxBridging ligandChemistryLigand (biochemistry)Combinatorial chemistryCrystallographyComputer scienceInorganic chemistryCrystal structureReceptorBiochemistryComputer securityMagnetism in coordination complexesLanthanide and Transition Metal ComplexesOrganic and Molecular Conductors Research