Mapping catalyst activation, turnover speciation and deactivation in Rh/PPh<sub>3</sub>-catalysed olefin hydroformylation
Alejandro Bara‐Estaún, Catherine L. Lyall, John P. Lowe, Paul G. Pringle, Paul C. J. Kamer, Robert Franke, Ulrich Hintermair
Abstract
Quantitative 31 P operando FlowNMR spectroscopy allows chartering the unknown territory of catalyst speciation under process conditions.
Topics & Concepts
HydroformylationCatalysisGenetic algorithmOlefin fiberChemistryOrganic chemistryRhodiumBiologyEcologyOrganometallic Complex Synthesis and CatalysisAsymmetric Hydrogenation and CatalysisMachine Learning in Materials Science