Uptake, Trapping, and Release of Organometallic Cations by Redox-Active Cationic Hosts
Iram F. Mansoor, Kaitlyn G. Dutton, Daniel A. Rothschild, Richard C. Remsing, Mark C. Lipke
Abstract
. This finding shows that metastable host-guest complexes can respond to subtler stimuli than those required to induce guest release from thermodynamically favorable complexes.
Topics & Concepts
ChemistryCationic polymerizationNanocagesPorphyrinDissociation (chemistry)RedoxStereochemistryPhotochemistryMetalCrystallographyMedicinal chemistryCatalysisPolymer chemistryInorganic chemistryOrganic chemistrySupramolecular Chemistry and ComplexesMetal-Organic Frameworks: Synthesis and ApplicationsMolecular Sensors and Ion Detection