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Solvation Structure Tuning Induces LiF/Li<sub>3</sub>N‐Rich CEI and SEI Interfaces for Superior Li/CF<i><sub>x</sub></i> Batteries (Small 49/2023)

Ping Li, Zhe Cheng, Jialu Liu, Lukang Che, Yingke Zhou, Enmin Xu, Xiaohui Tian, Zhongzhi Yuan

2023Small13 citationsDOIOpen Access PDF

Abstract

Li/CFx Batteries In article number 2303149, Yingke Zhou, Xiaohui Tian, Zhongzhi Yuan, and co-workers apply pentafluoropyridine (C5F5N) as an electrolyte additive to tune the characteristics of the solid-electrolyte interface (SEI) and cathode-electrolyte interface (CEI) for Li/CFx primary batteries. Benefiting from the tuned Li+ solvation structure and stable LiF/Li3N-rich CEI and SEI induced by C5F5N additive, superior discharge capacity, rate capability and storage performance are achieved.

Topics & Concepts

SolvationElectrolyteCathodeMaterials scienceChemical engineeringIonChemistryPhysical chemistryOrganic chemistryElectrodeEngineeringAdvanced Battery Materials and TechnologiesAdvancements in Battery MaterialsExtraction and Separation Processes