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Modified cyclodextrins solubilize elemental sulfur in water and enable biological sulfane sulfur delivery

Sarah G. Bolton, Michael D. Pluth

2020Chemical Science20 citationsDOIOpen Access PDF

Abstract

Sulfane sulfur, or S <sup>0</sup> , is found in polysulfide and persulfide compounds in biology. We demonstrate that modified cyclodextrins can solubilize S <sub>8</sub> in water, increase its reactivity with biological nucleophiles, and enable delivery to live cells.

Topics & Concepts

PolysulfideSulfurNucleophileSolubilizationReactivity (psychology)ChemistryCombinatorial chemistryOrganic chemistryBiochemistryPathologyAlternative medicinePhysical chemistryElectrodeMedicineCatalysisElectrolyteSulfur Compounds in BiologyGenomics, phytochemicals, and oxidative stressRedox biology and oxidative stress
Modified cyclodextrins solubilize elemental sulfur in water and enable biological sulfane sulfur delivery | Litcius