Reactive Hydrogen Species Behaviors on Pd/TiN: In Situ SERS Guided Regulation for Chemoselective Hydrogenation
Xiaoling Zhang, Qiushi Shen, Xinyu Li, Wen Li, Jiefang Sun, Jingfu Liu, Chunyang Liao, Sijin Liu, Guibin Jiang, Rui Liu
Abstract
Abstract Uncovering the H 2 dissociation and H‐spillover behaviors of the generated reactive hydrogen species on catalyst surfaces is crucial for achieving efficient and chemoselective hydrogenation. However, those behaviors remain largely elusive given the challenges of directly observing H atoms, the smallest atoms in the element table. Herein, we explored the Pd site–specific D 2 cleavage and the H‐spillover behaviors of dissociated D on the titanium nitride (TiN) support via in situ surface‐enhanced Raman spectroscopically (SERS). Besides facilitated forming Pd single atom (Pd 1 ), fully exposed Pd cluster (Pd n ) and Pd nanoparticles, dissociated D 2 on Pd sites (indicated by ν Pd–D at 1,800 cm −1 ), spillover to TiN, and formation of the N─D bond (indicated by ν N–D at 2,400 cm −1 ) were spectroscopically traceable. Combined with density functional theory (DFT) calculation, Pd n is identified as the most favorable site for the provision of reactive H through hydrogen spillover. Moreover, we propose ν Pd‐D and the ν N‐D /ν Pd‐D ratio as the index to relative amounts of Pd 1 and Pd n sites, respectively, and develop an in situ SERS‐based method to study the synthesis–structure–activity relationship of Pd/TiN catalyst with an optimized structure for chemoselective hydrogenation.