Taming the Lewis Superacidity of Non‐Planar Boranes: C−H Bond Activation and Non‐Classical Binding Modes at Boron
Arnaud Osi, Damien Mahaut, Nikolay Tumanov, Luca Fusaro, Johan Wouters, Benoı̂t Champagne, Aurélien Chardon, Guillaume Berionni
Abstract
Abstract The rational design of a geometrically constrained boron Lewis superacid featuring exceptional structure and reactivity is disclosed. It enabled the formation of non‐classical electron deficient B−H−B type of bonding, which was supported by spectroscopic and structural parameters as well as computational studies. Taming the pyramidal Lewis acid electrophilicity through weak coordinating anion dissociation enabled a series of highly challenging chemical transformations, such as Csp 2 −H and Csp 3 −H activation under a frustrated Lewis pair regime and the cleavage of Csp 3 −Si bonds. The demonstration of such rich chemical behaviour and flexibility on a single molecular compound makes it a unique mediator of chemical transformations generally restricted to transition metals.