Fungal degradation of reprocessed PP/PBAT/thermoplastic starch blends
Thainá Araújo de Oliveira, Renata Barbosa, Avilnete B.S. Mesquita, Josie Haydée Lima Ferreira, Laura Hécker de Carvalho, Tatianny Soares Alves
Abstract
It is well known that the inadequate disposal of polymeric materials causes significant environmental problems. Recycling and the use of biodegradable polymers are among the methods used to minimize these problems. However, the low mechanical performance of the majority of biodegradable polymers hinders the direct substitution of synthetic polymers, such as polyethylene (PE), polypropylene (PP) and polystyrene (PS), by biodegradable ones. Blending synthetic and biodegradable polymers is a way to develop recyclable biodegradable products with a good set of mechanical properties. Therefore, in this work we investigate the influence of extrusion cycles on the degradation of a polypropylene/poly (butylene adipate-co-terephthalate)/thermoplastic starch blend before and after inoculation with Aspergillus sp. and Penicillium sp. fungi degradaded for 30 days. The samples were exposed to the fungi and their mass loss, chemical structure, hydrophilicity, and morphology were observed as a function of inoculation time and processing cycles. Our results indicate that thermo-mechanical degradation favors the deposition of fungi in the samples and enables changes in film morphology and hydrophilicity.