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Corrosion Inhibition Study of Mild Steel in an Aqueous Hydrochloric Acid Solution Using Brilliant Cresyl Blue - a Combined Experimental and Monte Carlo Study

Авни Бериша, Fetah I. Podvorica, R Vataj

2021Portugaliae electrochimica acta26 citationsDOIOpen Access PDF

Abstract

Mild steel corrosion behaviour in a 0.5 M hydrochloric acid aqueous medium has been studied using potentiodynamic polarization measurements and Monte Carlo calculations, in the presence and absence of (7-Amino-8-methylphenoxazin-3-ylidene)-diethylazanium dichlorozinc dichloride [known as Brilliant Cresyl Blue (BCB) -dye]. Potentiodynamic measurements indicate that this compound acts as a slightly anodic inhibitor. Monte Carlo simulation was used to understand the studied molecules adsorption ability onto a Fe(1 1 0) surface, at the molecular level. The experimental results and theoretical calculations provided important support for the understanding of the corrosion inhibition mechanism adopted by this molecule.

Topics & Concepts

Hydrochloric acidAqueous solutionMonte Carlo methodCorrosionNuclear chemistryChemistryMaterials scienceInorganic chemistryOrganic chemistryMathematicsStatisticsConcrete Corrosion and DurabilityCorrosion Behavior and Inhibition