Structural, electrical, and magnetic study of La-, Eu-, and Er- doped bismuth ferrite nanomaterials obtained by solution combustion synthesis
Angelika Wrzesińska, Alexander Khort, Marcin Witkowski, Jacek Szczytko, Jacek Ryl, Jacek Gurgul, D. S. Kharitonov, K. Łątka, T. Szumiata, Aleksandra Wypych‐Puszkarz
Abstract
Abstract In this work, the multiferroic bismuth ferrite materials Bi 0.9 RE 0.1 FeO 3 doped by rare-earth (RE = La, Eu, and Er) elements were obtained by the solution combustion synthesis. Structure, electrical, and magnetic properties of prepared samples were investigated by X-ray photoelectron spectroscopy, Mössbauer spectroscopy, electrical hysteresis measurement, broadband dielectric spectroscopy, and SQUID magnetometry. All obtained nanomaterials are characterized by spontaneous electrical polarization, which confirmed their ferroelectric properties. Investigation of magnetic properties at 300.0 K and 2.0 K showed that all investigated Bi 0.9 RE 0.1 FeO 3 ferrites possess significantly higher magnetization in comparison to bismuth ferrites obtained by different methods. The highest saturation magnetisation of 5.161 emu/g at 300.0 K was observed for the BLaFO sample, while at 2.0 K it was 12.07 emu/g for the BErFO sample. Several possible reasons for these phenomena were proposed and discussed.