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Recent Advances in High-Entropy Oxides for Photocatalytic Applications

Hanzo Tsubota, Andrei Jitianu, Go Kawamura

2025ACS Materials Letters32 citationsDOIOpen Access PDF

Abstract

High Resolution Image Download MS PowerPoint Slide This paper provides a comprehensive overview of high-entropy oxides (HEOs) and their applications in photocatalysis. The unique functionality of HEOs stems from their distinct crystal and electronic structures, achieved through the substitution of one cation with multiple cations in the lattice. This structural innovation has attracted significant attention, with increasing studies since 2019. To date, approximately 38 papers on HEOs in photocatalysis have been reported, indicating that this research is still in its early stages. Some HEOs exhibit photocatalytic performance comparable to that of conventional oxides like TiO 2 and SrTiO 3, highlighting their potential. This Perspective discusses the synthesis methods, crystal structures, and photocatalytic properties of HEOs, emphasizing their advantages through specific examples. Additionally, it proposes future research directions, including the development of innovative materials and prediction of properties using first-principles calculations and machine learning, to advance the application of HEOs in photocatalysis.

Topics & Concepts

PhotocatalysisMaterials scienceNanotechnologyStatistical physicsEnvironmental scienceChemistryPhysicsOrganic chemistryCatalysisTransition Metal Oxide NanomaterialsCatalytic Processes in Materials ScienceElectronic and Structural Properties of Oxides
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