Homoallyl alcohol as an allylation reagent for termination of the Catellani–Lautens reaction <i>via</i> retro-allylation
Xueyan Du, Xiaozhe Yang, Han Wang, Xinguang Li, Murong Wang, Xiang Li, Tao Ye, Yaxing Yang, Xinqiang Tan, Feng Ren, Ping‐Xin Zhou, Yong‐Min Liang
Abstract
A palladium/norbornene-catalyzed ortho -amination/allylation of aryl iodides was developed for the construction of ortho -aminated allylbenzene by using N -benzoyloxyamine as the amination reagent and homoallyl alcohol as the allylation reagent.
Topics & Concepts
ChemistryReagentAminationNorborneneArylAlcoholOrganic chemistryMedicinal chemistryCatalysisCombinatorial chemistryCopolymerPolymerAlkylCatalytic Cross-Coupling ReactionsCatalytic C–H Functionalization MethodsAsymmetric Synthesis and Catalysis