Acetate exchange mechanism on a Zr <sub>12</sub> oxo hydroxo cluster: relevance for reshaping Zr–carboxylate coordination adaptable networks
Meenu Murali, Christian Bijani, Jean‐Claude Daran, Éric Manoury, Rinaldo Poli
Abstract
bridging acetates is associated to the release of ring strain. The results presented in this investigation may help the interpretation of carboxylate exchange phenomena in other systems and the design of new carboxylate-based materials.
Topics & Concepts
CarboxylateCluster (spacecraft)Mechanism (biology)Relevance (law)ChemistryCoordination complexCombinatorial chemistryStereochemistryComputer sciencePhysicsOrganic chemistryOperating systemMetalQuantum mechanicsPolitical scienceLawPolyoxometalates: Synthesis and ApplicationsMetal-Organic Frameworks: Synthesis and ApplicationsCarbon dioxide utilization in catalysis