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Cathodic Protection System against a Reverse-Current after Shut-Down in Zero-Gap Alkaline Water Electrolysis

Yoona Kim, Sang‐Mun Jung, Kyu‐Su Kim, Hyun-Yup Kim, Jaesub Kwon, Jinhyeon Lee, Hyun‐Seok Cho, Yong‐Tae Kim

2022JACS Au101 citationsDOIOpen Access PDF

Abstract

by the dissolution of a sacrificial metal to satisfy the above requirement; irreversible oxidization of the cathode is prevented by connecting a sacrificial anode to the Ni cathode. In the accelerated durability test under a simulated reverse-current condition, lead was found to be the most promising candidate for the sacrificial metal, as it is cost effective and demonstrates chemical stability in the alkaline media. A newly defined metric, a reverse-current stability factor, highlights that our system for protecting the cathode against the reverse-current is an efficient strategy for stable and cost effective alkaline hydrogen production.

Topics & Concepts

CathodeAnodeCathodic protectionElectrolysisMaterials scienceDegradation (telecommunications)Current (fluid)DissolutionElectrodeChemical engineeringChemistryElectrical engineeringElectrolyteEngineeringPhysical chemistryElectrocatalysts for Energy ConversionAdvanced battery technologies researchHybrid Renewable Energy Systems
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