Turn-on fluorescence sensors based on dynamic intramolecular N→B-coordination
Raphael Koch, Yu Sun, Andreas Orthaber, Antonio J. Pierik, Frank Pammer
Abstract
A series of ten aryl-triazole-functionalized boranes bearing BMes<sub>2</sub>-groups and capable of forming intramolecular five-membered N→B-coordinated heterocycles, has been prepared by 1,3-dipolar cycloaddition.
Topics & Concepts
Intramolecular forceChemistryBoranesCycloadditionFluorescenceArylTurn (biochemistry)Combinatorial chemistryStereochemistryOrganic chemistryCatalysisBoronAlkylBiochemistryQuantum mechanicsPhysicsLuminescence and Fluorescent MaterialsOrganoboron and organosilicon chemistrySulfur-Based Synthesis Techniques