Controllable redox reaction cycle enabled by multifunctional Ru-containing polyoxometalate-based catalysts
Huafeng Li, Zelong Yuan, Wenjing Chen, Mengnan Yang, Yahao Sun, Shihao Zhang, Pengtao Ma, Jingping Wang, Jingyang Niu
Abstract
Multifunctional Ru-POM catalysts implement path loops for the first time with a high TON of 485, 490, 3520 and 1980 for selective oxidation of AN to AOB, AB, NSB and NB, and a TON of 2000 for photocatalytic reduction of NB to AN, respectively.
Topics & Concepts
PolyoxometalateCatalysisTonRedoxPhotocatalysisChemistryRutheniumMaterials scienceChemical engineeringInorganic chemistryOrganic chemistryEngineeringFisheryBiologyPolyoxometalates: Synthesis and ApplicationsAdvanced Photocatalysis TechniquesAdvanced Nanomaterials in Catalysis