The Use of Copper and Vanadium Mineral Ores in Catalyzed Mechanochemical Carbon–Carbon Bond Formations
Francesco Puccetti, Christian Schumacher, Hermann Wotruba, José G. Hernández, Carsten Bolm
Abstract
Under mechanochemical conditions in ball mills, copper- and vanadium-containing minerals initiate atom transfer radical cyclizations and oxidative couplings, respectively. Only catalytic quantities of the minerals are required, and the reactions proceed either under neat conditions or in the presence of a minimal amount of solvent.
Topics & Concepts
VanadiumCopperCatalysisCarbon fibersMineralMetallurgyMaterials scienceChemistryInorganic chemistryChemical engineeringOrganic chemistryComposite numberComposite materialEngineeringRadical Photochemical ReactionsCatalytic C–H Functionalization MethodsAxial and Atropisomeric Chirality Synthesis