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Estimating cation exchange capacity from agronomic soil tests: Comparing Mehlich‐3 and ammonium acetate sum of cations

Tuomas Mattila, Jukka Rajala

2021Soil Science Society of America Journal33 citationsDOIOpen Access PDF

Abstract

Abstract Soil cation exchange capacity (CEC) measures the capability of soils to hold and release nutrients. It is an important measure for classifying soils and planning nutrient additions, but it is not included in routine soil tests offered to farmers. In this study, we compared CEC measured with standard laboratory practices (neutral ammonium acetate [AAc]) with CEC estimated from agronomic soil test data (Mehlich‐3 and AAc). We applied previously published estimation methods to a dataset of 48 soil samples. Based on the results, traditional methods underestimate measured cation exchange capacity by 36% for Mehlich‐3 and 24% for AAc. The estimation can be improved by including aluminium (12% overestimate) or by fitting a localized pedotransfer function (3% underestimate), which offers a possibility for informing land managers about their soil nutrient holding capacity without adding costs to the analysis.

Topics & Concepts

Cation-exchange capacityAmmonium acetatePedotransfer functionSoil waterNutrientAmmoniumEnvironmental scienceSoil testSoil scienceChemistryEnvironmental chemistryChromatographyHydraulic conductivityOrganic chemistryHigh-performance liquid chromatographySoil and Water Nutrient DynamicsSoil Carbon and Nitrogen DynamicsSoil and Unsaturated Flow
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