Recent advances in photochemical construction of aromatic C–P bonds <i>via</i> C–hetero bond cleavage
Qian Dou, Taimin Wang, Bin Cheng, Chao‐Jun Li, Huiying Zeng
Abstract
Photochemical synthesis is flourishing in recent years, which has provided new and efficient methods for aromatic C-P bond formation. This review summarises the recent advances in photochemical C-P bond cross-couplings in aromatics, enriching the synthetic methods of phosphorus containing compounds. Photosensitizer-catalyzed and photosensitizer-free reactions are reviewed. Different types of bond cleavages for substrates, such as C-X (X = F, Cl, Br, I), C-N and C-O bond cleavage, are discussed in three categories.
Topics & Concepts
ChemistryCleavage (geology)Bond cleavagePhotochemistryStereochemistryOrganic chemistryCatalysisFracture (geology)EngineeringGeotechnical engineeringRadical Photochemical ReactionsSulfur-Based Synthesis TechniquesCatalytic C–H Functionalization Methods